Acentric three-dimensional coordination polymers bis(isonicotinato)zinc (1) and bis(4-pyridylacrylato)cadmium⋅H O (2) were synthesized under hydro(solvo)thermal conditions; they exhibit a threefold (see picture) and fivefold diamondoid structure, respectively. Both 1 and 2 are active for second harmonic generation and exhibit remarkable thermal stability.
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| http://dx.doi.org/10.1002/(SICI)1521-3773(19990215)38:4<536::AID-ANIE536>3.0.CO;2-3 | DOI Listing |
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