New framework materials composed of well-defined vanadium oxide clusters were prepared by low-temperature reactions and characterized by X-ray crystal structure analysis. The structures of these solids contain {V O } cages linked into two interpenetrating three-dimensional networks by bridging {M(H O) } groups (M=Fe , Co ; see picture).

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http://dx.doi.org/10.1002/(SICI)1521-3773(19990503)38:9<1292::AID-ANIE1292>3.0.CO;2-2DOI Listing

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