Alkylation of Porous Silicon by Direct Reaction with Alkenes and Alkynes.

Angew Chem Int Ed Engl

Department of Chemistry, University of Newcastle-upon-Tyne, Newcastle-upon-Tyne, NE1 7RU (UK), Fax: (+44) 191-222-6929.

Published: October 1998

The hydrogen-terminated surface of porous silicon (PS) is sufficiently reactive for the uncatalyzed hydrosilation of alkenes and alkynes. These modifications produce dramatic changes to both the physical and chemical properties of the PS.

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http://dx.doi.org/10.1002/(SICI)1521-3773(19981016)37:19<2683::AID-ANIE2683>3.0.CO;2-YDOI Listing

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