Despite its preferred equatorial conformation in the solid state and in solution, the cis,cis-trispiro ether 1 binds readily and strongly to lithium ions. The 2:1 sandwich complex 2 is initially formed and transformed progressively into the 1:1 species 3 upon the addition of more LiClO .
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A Belted Monofacial Ionophore Featuring High Selectivity for Lithium Ion Complexation.
Angew Chem Int Ed Engl
May 1999
Department of Chemistry, The University of Alabama, Tuscaloosa, AL 35487 (USA).
Despite its preferred equatorial conformation in the solid state and in solution, the cis,cis-trispiro ether 1 binds readily and strongly to lithium ions. The 2:1 sandwich complex 2 is initially formed and transformed progressively into the 1:1 species 3 upon the addition of more LiClO .
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