Hydrogen-Bonding Cavities about Metal Ions: A Redox Pair of Coordinatively Unsaturated Paramagnetic Co-OH Complexes.

Angew Chem Int Ed Engl

Department of Chemistry, University of Kansas, Lawrence, KS 66045 (USA), Fax: (+1) 785-864-5396.

Published: March 1999

Nature uses hydrogen bonds to regulate a variety of metal-based reactions. These effects are emulated in the stabilization of trigonal-bipyramidal, paramagnetic Co-OH complexes such as the mono- or dianionic redox-active complex 1 by use of a new hydrogen-bonding ligand.

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http://dx.doi.org/10.1002/(SICI)1521-3773(19990301)38:5<666::AID-ANIE666>3.0.CO;2-XDOI Listing

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