AI Article Synopsis
- The pH levels influence the self-condensation of the [Mo S O] complex, leading to the formation of a wheellike Mo cluster.
- The representation of the cluster uses a ball-and-stick model to illustrate the different elements (Mo, S, O).
- This synthetic method could potentially be adapted for different starting materials to create various polyoxothiometalates with distinct cavity structures.
Article Abstract
The pH-dependent self-condensation of the [Mo S O ] complex fragment gives the wheellike Mo cluster depicted on the right (ball-and-stick model; large balls: S, medium balls: O, small balls: Mo). Applying this synthetic strategy to other starting materials could provide access to other polyoxothiometalates with well-defined cavities.
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| http://dx.doi.org/10.1002/(SICI)1521-3773(19980316)37:5<611::AID-ANIE611>3.0.CO;2-O | DOI Listing |
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