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Metal--Metal "Communication" of Rh or Pd with Nd in Novel Heterobinuclear Complexes. | LitMetric

Metal--Metal "Communication" of Rh or Pd with Nd in Novel Heterobinuclear Complexes.

Angew Chem Int Ed Engl

Abt. Komplexkatalyse, Institut für Organische Katalyseforschung an der Universität, Buchbinderstrasse 5-6, D-18055 Rostock (Germany), Fax: (+49) 381-466-9374.

Published: August 1998

The reaction of a neodymium "ate" complex and an electron-rich transition metal chloride by salt elimination is an efficient method for synthesizing heterobinuclear compounds which contain a lanthanide and a Group 9 or 10 metal [Eq. (1), H Ap=2-amino-4-methylpyridine]. The use of bisaminopyridinato ligands allows extremely short distances between Rh or Pd and Nd.

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http://dx.doi.org/10.1002/(SICI)1521-3773(19980817)37:15<2079::AID-ANIE2079>3.0.CO;2-YDOI Listing

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