Significantly different coordination spheres are displayed by the two central atoms of 2, the first representative of a novel type of mixed-valence dinuclear Rh -Rh compound, which was synthesized from the stibane-bridged complex 1. The Rh-Rh distance determined by an X-ray crystal structure analysis of 2 indicates a metal-metal interaction between the two metal centers.
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| http://dx.doi.org/10.1002/(SICI)1521-3773(19990601)38:11<1609::AID-ANIE1609>3.0.CO;2-P | DOI Listing |
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