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Homoallyl-Substituted Vinylcyclopropanes from α,β-Unsaturated Ketones and Allylindium Derivatives. | LitMetric

Homoallyl-Substituted Vinylcyclopropanes from α,β-Unsaturated Ketones and Allylindium Derivatives.

Angew Chem Int Ed Engl

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS (UK), Fax: (+44) 117-929-8611.

Published: June 1998

AI Article Synopsis

Article Abstract

Simply reversing the order of addition of aqueous acid and Et O to the Barbier intermediate 1 of the known indium-mediated allylation leads to unprecedented deoxygenative rearrangements [Eq. (a)].

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Source
http://dx.doi.org/10.1002/(SICI)1521-3773(19980619)37:11<1545::AID-ANIE1545>3.0.CO;2-3DOI Listing

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Simply reversing the order of addition of aqueous acid and Et O to the Barbier intermediate 1 of the known indium-mediated allylation leads to unprecedented deoxygenative rearrangements [Eq. (a)].

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