Cultivating crystal lattice distortion in IrOvia coupling with MnO to boost the oxygen evolution reaction with high intrinsic activity.

Chem Commun (Camb)

State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Processes, School of Resources and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China.

Published: May 2018

Here, we report an effective strategy to lower Ir consumption and boost the OER performance in acid by loading IrO2 onto MnO2, in which the IrO2 crystals are well dispersed and undergo a so-called z-extension Jahn-Teller distortion in the octahedral structure. Compared with IrO2, the mass activity and intrinsic activity for IrO2/MnO2 were largely increased.

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Source
http://dx.doi.org/10.1039/c8cc02008fDOI Listing

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