A new 3D framework {[Eu Cu(IN) (CO )(H O)] ⋅3 H O} (1) was obtained and structurally characterized, containing Cu and an unusual lanthanide duplex chain. The luminescent explorations of compound 1 suggest that 1 could emit the characteristic emission of Cu , and 1 can act as the luminescent sensor of ClO with the detection limit of 10 m. Notably, 1 represents the first example of MOF-based sensor for detecting ClO .
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| http://dx.doi.org/10.1002/chem.201801071 | DOI Listing |
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