Ion-doped poly(p-phenylenediamine) (Fe-ppd) nanoparticles were prepared at room temperature by using FeCl3 as an oxidant. Fe-ppd exhibited high photothermal conversion efficiency (39.27%) and excellent photostability. In vitro and in vivo evaluation demonstrated that Fe-ppd could be used as an ideal photothermal agent for photothermal therapy for the first time.
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http://dx.doi.org/10.1039/c8cc01100a | DOI Listing |
J Phys Chem B
January 2025
Science and Technology on Aerospace Chemical Power Laboratory, Laboratory of Emergency Safety and Rescue Technology, Hubei Institute of Aerospace Chemotechnology, Xiangyang 441003, China.
Doped semiconductors are often used to improve photocatalytic efficiency and address the challenges of easy recombination of electron-hole pairs and poor photoluminescence. However, the reproducibility and complexity of experimental studies result in time-consuming and less cost-effective studies, and it is difficult to gain insights into the intrinsic properties of doped photocatalysts to control their performance. Introducing a machine learning approach, we constructed a photocatalytic model of transition-metal- and rare earth metal-ion-doped γ-BiMoO.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
College of Chemistry and Material Science, Anhui Carbon Neutrality Engineering Center, Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University, Wuhu 241000, China.
Given the immense potential for addressing energy and environmental issues, the utilization of solar energy for hydrogen production by water splitting (WS) has garnered widespread attention in the scientific community. Perovskite oxides (POs), with their compositional flexibility and structural stability, hold significant promise in the photocatalytic hydrogen evolution reaction (HER). Rational doping of POs is the key to enhancing the rate of the photocatalytic HER.
View Article and Find Full Text PDFInorg Chem
December 2024
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, P. R. China.
Zero-dimensional (0D) metal halides have emerged as excellent luminescent materials for optical and optoelectronic applications. Especially environmentally friendly ternary zinc halides have recently drawn increasing attention. Herein, we present the codoping of Cu and Mn ions into 0D CsZnBr single crystals (SCs), which show bright PL emission and high stability.
View Article and Find Full Text PDFJ Trace Elem Med Biol
November 2024
Institute of Biomaterials, University of Erlangen-Nuremberg, Erlangen 91058, Germany. Electronic address:
Introduction: The incorporation of trace elements such as strontium (Sr) and copper (Cu) in the composition of mesoporous bioactive glass (MBG) is widely known to enhance its biological functionality for bone tissue regeneration METHODS: Two MBG powders with the composition 80SiO-11CaO-5PO-xCuO/SrO, one doped with 4 mol.% of CuO, the second with 4 mol.% of SrO were blended in the weight ratios of Cu-MBG: Sr-MBG; 100:0, 70: 30, 50: 50, 30: 70 and 0:100 aiming at minimizing Cu to minimize the cytotoxicity of Cu while preserving its antimicrobial activity.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
School of Materials Sciences, Indian Association for the Cultivation of Science, Jadavpur, Kolkata-700032, India.
Atomically precise two-dimensional (2D) semiconductor nanoplatelets (NPLs) are found to be promising materials for next-generation optoelectronic devices due to their excellent optical properties. However, energy loss through phonon emission significantly causes problems in achieving efficient performance. Power-dependent steady-state spectroscopy and ultrafast spectroscopic studies have been performed to understand the influence of Ag ions on ultrafast carrier dynamics and thermalization processes in colloidal CdSe NPLs.
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