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Stable lead(ii) boroxides. | LitMetric

Stable lead(ii) boroxides.

Chem Commun (Camb)

Supramolecular Organic and Organometallic Chemistry Centre, Chemistry Department, Faculty of Chemistry and Chemical Engineering, Babes-Bolyai University, Cluj-Napoca RO-400028, Romania.

Published: May 2018

AI Article Synopsis

Article Abstract

The first examples of lead(ii) boroxides, [Pb(OB{CH(SiMe3)2}2)2] (1) and [{N^C}PbOB{CH(SiMe3)2}2] (5; N^C = 2-Me2NCH2C6H4), were prepared via simple protocols. These structurally characterised compounds are stable and, unlike lead(ii) alkoxides and siloxides, do not trigger uncontrolled formation of lead(ii) oxoclusters.

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Source
http://dx.doi.org/10.1039/c8cc02459fDOI Listing

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