Temperature dependent separation of immiscible polymer blend in a melted state.

The density and the spectral fingerprint of a compounded blend or composite vary widely depending on the type of the components and their composition. However, the currently used polymer separation techniques, such as density-based and optical sorting systems are not suitable for recovering these materials fully due to the physical-chemical bonding between the components. The application of a novel separation principle creates the opportunity to enrich the blend fractions to neat, homogeneous zones in a melted state by utilising centrifugal force. In this study three different types of plastics: high density polyethylene, polystyrene and polyethylene terephthalate were deeply investigated in order to understand the separability of their blends as a function of rotation time and melt temperature. The results showed that the separation of polymer mixtures and blends depends strongly on the viscosity and bulk density at a given temperature, and the initial particle size also has a significant impact.