Co/Cr-Decorated Carbon Nanofibers as Novel and Efficacious Electrocatalyst for Ethanol Oxidation in Alkaline Medium.

In this work, Co/Cr nanoparticles-decorated carbon nanofibers were studied as a platinum-free catalyst for electrooxidation of ethanol in the alkaline medium. The investigated nano composites were prepared by simple, high yield and effective technique; electrospinning of cobalt acetate, chromium acetate and polyvinyl alcohol as a polymer precursor at 20 kV followed by calcination under inert atmosphere at 900 °C for 2 h. The suitable physicochemical characterizations such as XRD, SEM, TEM, TEM mapping, Line TEM-EDX and FE-SEM indicated the formation of pure CoCr nanoparticles allocated in/on carbon nanofibers. Electro catalytic activity measurements showed that the investigated Co–Cr carbon nanofibers can be effectively utilized in ethanol electrooxidation in 1 mol/l KOH solution. The observed current density was 105 mA/cm2 which is considered high value for non-precious electrocatalyst. Also, study the influence of Cr content in Cr–Co alloy toward ethanol oxidation was investigated to obtain the most effective composition. The suitable Cr concentration found to be 10% of Co content.