Cation-dependent reactions "[SbBr ] +Br +HBr+CationBr " result in the formation of bromide/polybromide complexes with zero-, one-, two-, or three-dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1-4.6 kcal mol ).
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Bromo- and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen-Rich Halometalate Frameworks.
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July 2018
Nikolaev Institute of Inorganic Chemistry SB RAS, 630090, Lavrentieva St. 3, Novosibirsk, Russia.
Cation-dependent reactions "[SbBr ] +Br +HBr+CationBr " result in the formation of bromide/polybromide complexes with zero-, one-, two-, or three-dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1-4.
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