Chiral separation and characterization of triazatruxene-based face-rotating polyhedra: the role of non-covalent facial interactions.

Chem Commun (Camb)

State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) and Key Laboratory of Chemical Biology of Fujian Province, Xiamen University, Xiamen 361005, P. R. China.

Published: May 2018

We constructed a series of novel chiral molecular face-rotating polyhedra (FRP) from two 10,15-dihydro-5H-diindolo[3,2-a:3',2'-c]carbazole (triazatruxene) derivatives and trans-1,2-cyclohexane diamine, and investigated how facial interactions and the positions of substituents determine the diastereoselectivity and geometry of the final assemblies.

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Source
http://dx.doi.org/10.1039/c8cc02049cDOI Listing

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