We report on a facile and environmentally friendly synthetic approach for single-crystalline chromium(II) carboxylate metal-organic frameworks (i.e., Cr(BTC)·3HO (1) and Cr(hfipbb)·HO (2) at room temperature in water. Both MOFs can be easily dehydrated, affording single-crystalline materials with open Cr(II) sites. In addition, the redox activity and porosity of the resulting Cr(II) MOFs were examined.
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| http://dx.doi.org/10.1021/acs.inorgchem.8b00395 | DOI Listing |
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