The electrochemical performance of most transition metal oxides based on the conversion mechanism is greatly restricted by inferior cycling stability, rate capability, high overpotential induced by the serious irreversible reactions, low electrical conductivity, and poor ion diffusivity. To mitigate these problems, highly porous Mn O micro/nanocuboids with in situ formed carbon matrix (denoted as Mn O @C micro/nanocuboids) are designed and synthesized via a one-pot hydrothermal method, in which glucose plays the roles of a reductive agent and a carbon source simultaneously. The carbon content, particle size, and pore structure in the composite can be facilely controlled, resulting in continuous carbon matrix with abundant pores in the cuboids. The as-fabricated Mn O @C micro/nanocuboids exhibit large reversible specific capacity (879 mAh g at the current density of 100 mA g ) as well as outstanding cycling stability (86% capacity retention after 500 cycles) and rate capability, making it a potential candidate as anode material for lithium-ion batteries. Moreover, this facile and effective synthetic strategy can be further explored as a universal approach for the synthesis of other hierarchical transition metal oxides and carbon hybrids with subtle structure engineering.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1002/smll.201704296 | DOI Listing |
Nat Commun
January 2025
School of Physical Science and Technology, Ningbo University, Ningbo, 315211, China.
The high performance of two-dimensional (2D) channel membranes is generally achieved by preparing ultrathin or forming short channels with less tortuous transport through self-assembly of small flakes, demonstrating potential for highly efficient water desalination and purification, gas and ion separation, and organic solvent waste treatment. Here, we report the construction of vertical channels in graphene oxide (GO) membrane based on a substrate template with asymmetric pores. The membranes achieved water permeance of 2647 L m h bar while still maintaining an ultrahigh rejection rate of 99.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
Food Inspection and Quarantine Technology Center of Shenzhen Customs, Shenzhen Academy of Inspection and Quarantine, Shenzhen, 518045, PR China.
Background: Ochratoxin A (OTA) is toxic secondary metabolites produced by fungi and can pose a serious threat to food safety and human health. Due to the high stability and toxicity, OTA contamination in agricultural products is of great concern. Therefore, the development of a highly sensitive and reliable OTA detection method is crucial to ensure food safety.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 43200, China.
Passive Radiant Cooling and Heating are green and sustainable methods of radiant heat management without consuming additional energy. However, the absorption of sunlight and poor insulation of materials can reduce radiative cooling and also affect radiative heating performance. Herein, we have constructed porous hierarchical dual-mode silk nanofibrous aerogel (SNF) films with high mechanical toughness and stability using silk nanofibers/GO.
View Article and Find Full Text PDFAdv Colloid Interface Sci
January 2025
School of Metallurgy and Environment, Central South University, Changsha 410083, Hunan, China; Chinese National Engineering Research Center for Control & Treatment of Heavy Metal Pollution, Institute of Environmental Engineering, Central South University, Changsha 410083, Hunan, China.
Rare earth elements (REEs) are crucial metallic resources that play an essential role in national economies and industrial production. The reclaimation of REEs from wastewater stands as a significant supplementary strategy to bolster the REEs supply. Adsorption techniques are widely recognized as environmentally friendly and sustainable methods for the separation of REEs from wastewater.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China.
Coordinatively unsaturated copper (Cu) has been demonstrated to be effective for electrifying CO reduction into C products by adjusting the coupling of C-C intermediates. Nevertheless, the intuitive impacts of ultralow coordination Cu sites on C products are scarcely elucidated due to the lack of synthetic recipes for Cu with low coordination numbers and its vulnerability to aggregation under reductive potentials. Herein, computational predictions revealed that Cu sites with higher levels of coordinative unsaturation favored the adsorption of C and C intermediates.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!