Synthesis and Unique Optical Properties of Selenophenyl BODIPYs and Their Linear Oligomers.

J Org Chem

Graduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS) , University of Tsukuba, 1-1-1 Tennodai , Tsukuba , Ibaraki 305-8571 , Japan.

Published: May 2018

A series of selenophene-substituted boron-dipyrrin (BODIPY) monomers and selenophene-linked BODIPY oligomers was synthesized. The synthesized BODIPYs show good absorption/emission properties in the red to near-infrared region. Furthermore, some of the selenophenyl BODIPYs are not only useful fluorophores but also good photosensitizers to produce singlet oxygen.

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http://dx.doi.org/10.1021/acs.joc.8b00782DOI Listing

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