Diketopyrrolopyrrole-Based Metallated Polymer for Bulk-Heterojunction Solar Cells and Organic Field-Effect Transistors.

We report the synthesis and optoelectronic properties of novel platinum-based polymers (p-Pt-DPP) incorporating 3,6-di-2-thienyl-2,5-dihydro-2,5-diethylhexylpyrrolo[3,4-c]pyrrole-1,4-dione. The synthesized amorphous metallated polymer exhibited long wavelength absorption in the range of 500–684 nm and a band-gap as low as 1.75 eV. Organic field-effect transistors (OFETs) fabricated from p-Pt-DPP showed hole mobility of 1.6 × 10⁻³ cm² · V⁻¹s⁻¹ and an on/off ratio of 5 × 10⁴. In addition, polymer solar cells (PSCs) based on p-Pt-DPP and PC₇₁BM exhibited a photovoltaic efficiency of 1.22% under AM 1.5 G conditions with an illumination of 100 mW·cm−2 without any annealing process.