Impactful regioselectivity control is crucial for cost-effective chemical synthesis. By using cheap and abundant iron(iii) salts, the hydroxycarbonylations of both aromatic and aliphatic alkenes were significantly enhanced in both reactivity and selectivity (iso/n or n/iso up to >99 : 1). Moreover, Pd-catalyzed carbonylation selectivity can be switched from branched to linear by using different Fe(iii) salts. In addition, similar results were obtained for the carbonylation of secondary alcohols.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c8cc01190g | DOI Listing |
Publication Analysis
Top Keywords
ironiii salts
8
regioselectivity inversion
4
inversion tuned
4
tuned ironiii
4
salts palladium-catalyzed
4
palladium-catalyzed carbonylations
4
carbonylations impactful
4
impactful regioselectivity
4
regioselectivity control
4
control crucial
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!