Photoluminescence measurements in mono- and bilayer-MoS on SiO were undertaken to determine the thermal effect of the MoS/SiO interface on the optical bandgap. The energy and intensity of the photoluminescence from monolayer MoS were lower and weaker than those from bilayer MoS at low temperatures, whilst the opposite was true at high temperatures above 200 K. Density functional theory calculations suggest that the observed optical bandgap crossover is caused by a weaker substrate coupling to the bilayer than to the monolayer.
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http://dx.doi.org/10.1038/s41598-018-23788-3 | DOI Listing |
Sci Rep
December 2024
Department of Physics, Faculty of Science, Islamic University of Madinah, Madinah 42351, Saudi Arabia.
Modifying ZnO nanorods with graphene oxide (GO) is crucial for enhancing photocatalytic degradation by boosting the concentration of reactive oxygen species (ROS) in the reaction medium. In this study, we present a straightforward chemical synthesis of ZnO nanorods embedded on GO, forming a novel nanocomposite, GOZ. This composite serves as an efficient photocatalyst for the sunlight-driven degradation of methylene blue (MB) and ciprofloxacin (CIP).
View Article and Find Full Text PDFNano Lett
December 2024
Wyant College of Optical Sciences, University of Arizona, 1630 East University Boulevard, Tucson, Arizona 85721, United States.
Microscopic many-body models based on inputs from first-principles density functional theory are used to calculate the carrier losses due to free carrier Auger-Meitner recombination (AMR) processes in Mo- and W-based monolayer transition metal dichalcogenides as a function of the carrier density, temperature, and dielectric environment. Despite the exceptional strength of Coulomb interaction in the two-dimensional materials, the AMR losses are found to be similar in magnitude to those in conventional III-V-based quantum wells for the same wavelengths. Unlike the case in III-V materials, the losses show nontrivial density dependencies due to the fact that bandgap renormalizations on the order of hundreds of millielectronvolts can bring higher bands into or out of resonance with the optimal energy level for the AMR transition, approximately one bandgap from the lowest band.
View Article and Find Full Text PDFAcc Chem Res
December 2024
Tarpo Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, United States.
ConspectusOrganic mixed ionic electronic conductors (OMIECs) represent an exciting and emerging class of materials that have recently revitalized the field of organic semiconductors. OMIECs are particularly attractive because they allow both ionic and electronic transport while retaining the inherent benefits of organic semiconducting materials such as mechanical conformability and biocompatibility. These combined properties make the OMIECs ideal for applications in bioelectronics, energy storage, neuromorphic computing, and electrochemical transistors for sensing.
View Article and Find Full Text PDFJ Phys Condens Matter
December 2024
Department of Physics, Indian Institute of Technology Delhi, IIT Delhi, Hauz Khas, New Delhi, Delhi, 110016, INDIA.
We have grown (111)- and (001)-oriented NiO thin films on (0001)-Sapphire and (001)-MgO substrates using pulsed laser deposition (PLD), respectively. DC magnetic susceptibility measurements underline that the Néel temperatures of the samples are beyond room-temperature. This is further confirmed by the presence of two-magnon Raman scattering modes in these films in ambient conditions.
View Article and Find Full Text PDFTalanta
December 2024
Thin Films and Materials Science Research Laboratory, Department of Physics, Dayanand Science College, Latur, Maharashtra, 413512, India. Electronic address:
In this study, we report the synthesis, optical characterization and ultra-sensitive ammonia gas sensing properties of Mg-doped ZnO cauliflower like nanostructures obtained via chemical spray pyrolysis technique. The morphological and structural properties of the prepared films were investigated by Field Emission Scanning electron microscope (FESEM) and X-ray diffraction (XRD). Gas sensing and optical characterizations were carried out using Keithley electrometer and Uv-Vis.
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