In a Bernal graphene bilayer, carbon atoms belong to two inequivalent sublattices A and B, with atoms that are coupled to the other layer by [Formula: see text] bonds belonging to sublattice A and the other atoms belonging to sublattice B. We analyze the density of states and the conductivity of Bernal graphene bilayers when atoms of sublattice A or B only are randomly functionalized. We find that for a selective functionalization on sublattice B only, a mobility gap of the order of 0.5 eV is formed close to the Dirac energy at concentration of adatoms [Formula: see text]. In addition, at some other energies conductivity presents anomalous behaviors. We show that these properties are related to the bipartite structure of the graphene layer.
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http://dx.doi.org/10.1088/1361-648X/aaba06 | DOI Listing |
Cureus
December 2024
Department of Physiology, Government Erode Medical College, Perundurai, IND.
Background: According to the World Health Organization (WHO), early mobilization is a critical component of healthcare that significantly impacts patient recovery and outcomes. Despite evidence supporting the benefits of early mobilization for abdominal surgery patients, standardized protocols remain scarce across many healthcare environments.
Aim: This study evaluates the feasibility and impact of an early mobility protocol (EMP) on improvement in mobility and patient satisfaction in abdominal surgery patients.
Chemistry
January 2025
Yanshan University, Physics, Hebeidajie,438, 066004, Qinhuangdao, CHINA.
Identifying two-dimensional (2D) high-efficiency solar photovoltaic devices remains an urgent challenge in addressing current energy demands. Considering the limits of isolated 2D systems in photovoltaics, one most effective solution is stacking them into van der Waals heterostructures (vdWHs). However, the favorable factors for photovoltaics in vdWHs is still uncertain, nor the intrinsic principles is clear.
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January 2025
Electric Mobility and Tribology Research Group, Council of Scientific and Industrial Research Central Mechanical Engineering Research Institute, Mahatma Gandhi Avenue, Durgapur, West Bengal, 713209, India.
Integration of different active sites by heterostructure engineering is pivotal to optimize the intrinsic activities of an oxygen electrocatalyst and much needed to enhance the performance of rechargeable Zn-air batteries (ZABs). Herein, a biphasic nanoarchitecture encased in in situ grown N-doped graphitic carbon (MnO/Co-NGC) with heterointerfacial sites are constructed. The density functional theory model reveals formation of lattice oxygen bridged heterostructure with pyridinic nitrogen atoms anchored Co species, which facilitate adsorption of oxygen intermediates.
View Article and Find Full Text PDFBMJ Case Rep
January 2025
Department of Rehabilitation Physiotherapy, National Center of Neurology and Psychiatry, Tokyo, Japan.
We report a case of amyotrophic lateral sclerosis (ALS) in a patient in their 50s, presenting with spastic paraparesis and bulbar palsy, treated with lung volume recruitment therapy (LVRT). From early stage in the disease, vital capacity (VC), lung insufflation capacity (LIC) and ALS Functional Rating Scale-Revised scores were regularly measured, and LVRT was continuously performed at home. After 10 years, the patient had complete limb function loss and required nutritional management via gastrostomy and full assistance with daily activities.
View Article and Find Full Text PDFNat Commun
January 2025
Morphing Matter Lab, Human-Computer Interaction Institute, Carnegie Mellon University, Pittsburgh, PA, USA.
Compliant mechanisms with reconfigurable degrees of freedom are gaining attention in the development of kinesthetic haptic devices, robotic systems, and mechanical metamaterials. However, available devices exhibit limited programmability and form-customizability, restricting their versatility. To address this gap, we propose a metastructure concept featuring reconfigurable motional freedom and tunable stiffness, adaptable to various form factors and applications.
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