The energy-rich methanofullerenes were synthesized for the first time by the reaction of fullerene C with mono- and bisquadricyclane esters of malonic acid. The C-C bond cleavage in the quadricyclane moieties of new hybrid molecules takes place in the presence of catalytic amounts of Cu, Pd, and Pt salts or complexes or SiO and is accompanied by heat evolution.
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Synthesis and Properties of Energy-Rich Methanofullerenes Containing Norbornadiene and Quadricyclane Moieties.
J Org Chem
April 2018
Laboratory of Catalytic Synthesis , Institute of Petrochemistry and Catalysis of RAS (IPC RAS), Prospect Octyabrya, 141 , 450075 Ufa , Russian Federation.
The energy-rich methanofullerenes were synthesized for the first time by the reaction of fullerene C with mono- and bisquadricyclane esters of malonic acid. The C-C bond cleavage in the quadricyclane moieties of new hybrid molecules takes place in the presence of catalytic amounts of Cu, Pd, and Pt salts or complexes or SiO and is accompanied by heat evolution.
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