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Synthesis of Hydrazines via Radical Generation and Addition of Azocarboxylic tert-Butyl Esters. | LitMetric
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Synthesis of Hydrazines via Radical Generation and Addition of Azocarboxylic tert-Butyl Esters.

Chen-Hao Ru Shi-Huan Guo Gao-Fei Pan Xue-Qing Zhu Ya-Ru Gao Yong-Qiang Wang

Org Lett

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry & Materials Science , Northwest University, Xi'an 710069 , P. R. China.

Published: April 2018

A new chemistry of azo compounds that is a radical generation and addition in situ of azocarboxylic tert-butyl esters to synthesize hydrazines has been described. The protocol provides a novel strategy for the synthesis of various hydrazines. The advantages of the transformation include broad substrate scope, benign conditions, and convenient operation.

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 Source
http://dx.doi.org/10.1021/acs.orglett.8b00448DOI Listing

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