Multifunctional vinyl sulfonates and vinyl sulfonamides were conveniently synthesized and assessed in thiol-Michael crosslinking polymerizations. The monomer reactivities, mechanical behavior and hydrolytic properties were analyzed and compared with those of analogous thiol-acrylate polymerizations. Materials with a broad range of mechanical properties and diverse hydrolytic stabilities were obtained.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5875713PMC
http://dx.doi.org/10.1039/c8cc00782aDOI Listing

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