1,3,5-Triphospha-1,4-pentadiene-2,4-diamine reacts with [M(CO)L] (M = Mo, L = nbd (norbornadiene); M = W, L = 2 CHCN) to give the chelate complexes [M(CO)(PMes{C(NHCy)PMes}-κ P ,P)]. In contrast, an unusual intramolecular rearrangement occurred with [Cu(CHCN)]PF leading to the dimeric copper(I) complex [Cu(CNCy){PHMesPMesC(NHCy)PMes-κ P ,P}](PF). The mechanism of the rearrangement was supported by quantum-mechanical calculations. The transition-metal complexes were characterized by multinuclear NMR spectroscopy, mass spectrometry, infrared spectroscopy, and X-ray crystallography.
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| http://dx.doi.org/10.1021/acs.inorgchem.8b00067 | DOI Listing |
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