Saccharomyces cerevisiae and nanoparticles of iron oxide (FeO) which were linked with chitosan (CS) through epichlorohydrin (ECH) were encapsulated in calcium alginate to prepare a novel type of bionanocomposites. Characterization results showed that the FeO-ECH-CS nanoparticles were quasi-spherical with an average diameter of 30 nm to which chitosan was successfully attached through epichlorohydrin. The saturation magnetization value of the nanoparticles was 21.88 emu/g, and ferrous and ferric irons were simultaneously observed in the magnetic nanoparticles. Data of atrazine removal by yeasts showed that both inactivated and live yeasts could decrease the concentration of atrazine effectively. The inactivated yeasts achieved 20% removal rate, which indicated that adsorption by the yeasts also played a role in the removal. Removal efficiency of atrazine was maximized at 88% under 25 °C, pH of 7 and an initial atrazine concentration of 2 mg/L. When the magnetic bionanocomposite was recycled and reused twice, only 12% and 20% drop in removal efficiency was observed at the first time and the second time severally. So, atrazine could be used by the yeasts as the sole carbon source for growth and multiplication, and both adsorption and biodegradation by the bionanocomposite contributed to atrazine removal.
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http://dx.doi.org/10.1016/j.chemosphere.2018.02.020 | DOI Listing |
Water Res
December 2024
Key Laboratory of the Three Gorges Reservoir Region's Eco-Environment, Ministry of Education, College of Environment and Ecology, Chongqing University, Chongqing 400045, China. Electronic address:
The peroxone reaction, a promising alternative technology for water treatment, is traditionally hampered by its restricted pH operational range and suboptimal oxidant utilization. In this study, we introduced a novel amphoteric metal oxide (ZnO)-regulated peroxone system that transcended the pH limitations of conventional peroxone processes. Our innovative approach exploited the unique properties of ZnO to regulate the reaction pathway of the traditional O/HO (or peroxymonosulfate, PMS) processes, resulting in a 52.
View Article and Find Full Text PDFInt J Phytoremediation
December 2024
Department of Ecology, Jinan University, Guangzhou, China.
Vegetated ditches have been demonstrated to be an effective method for pollutant remediation. This study assesses the removal potential and pathways for herbicide runoff pollution utilizing , , , and ditches. Resultes show these vegetated ditches significantly outperform unvegetated ones in removing atrazine and diuron during runoff events ( < 0.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
State Key Laboratory of Geohazard Prevention and Geoenvironment Protection (Chengdu University of Technology), Chengdu, Sichuan 610059, P.R. China; State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, P.R. China. Electronic address:
Electron mediator-based in-situ chemical oxidation (ISCO) offers a novel strategy for groundwater remediation due to diverse reaction pathways. However, distinguishing and further tuning the reaction pathway remains challenging. Herein, biochar as an electron mediator targeted active peroxysulphate (PDS) via the radical or non-radical pathway.
View Article and Find Full Text PDFJ Environ Sci Health B
December 2024
VNU Key Laboratory of Advanced Material for Green Growth, Faculty of Chemistry, VNU University of Science, Thanh Xuan, Hanoi, Vietnam.
Frequent use of pesticides results in the release of large quantities of their residues in the environment, raising various concerns for humans and the ecosystem. This work introduces a simple and cost-effective method for removal atrazine pesticide residue (APR) from agricultural wastewater using Cu doped-ZnO photocatalyst (Cu-ZnO). The modification of ZnO with Cu significantly improved its optical and photoelectrochemical properties, with the band gap narrowing from 3.
View Article and Find Full Text PDFEnviron Res
January 2025
Key Laboratory of Pollution Ecology and Environmental Engineering, Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016, China.
The widespread use of atrazine in agriculture threatens soil health and the safety of agricultural products. In this study, the removal and mechanism of green manure plants (GMPs) hairy vetch (Vicia villosa Roth, VV) and ryegrass (Lolium perenne L., LP) to atrazine were investigated.
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