We present an extreme ultraviolet (EUV) microscope using a Schwarzschild objective which is optimized for single-shot sub-micrometer imaging of laser-plasma targets. The microscope has been designed and constructed for imaging the scattering from an EUV-heated solid-density hydrogen jet. Imaging of a cryogenic hydrogen target was demonstrated using single pulses of the free-electron laser in Hamburg (FLASH) free-electron laser at a wavelength of 13.5 nm. In a single exposure, we observe a hydrogen jet with ice fragments with a spatial resolution in the sub-micrometer range. In situ EUV imaging is expected to enable novel experimental capabilities for warm dense matter studies of micrometer-sized samples in laser-plasma experiments.
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http://dx.doi.org/10.1063/1.5007950 | DOI Listing |
J Am Chem Soc
December 2024
Department of Chemical Engineering, University of California, Santa Barbara, California 93106, United States.
AC plasmas directly excited within liquid hydrocarbons were investigated for the production of hydrogen and unsaturated C hydrocarbon in a recirculating liquid "jet" flow configuration. Arc discharges were excited at two different frequencies (60 Hz and 17.3 kHz) in C-C hydrocarbons (hexane, cyclohexane, benzene, toluene, and xylene) to produce H, CH, CH, and CH, along with liquid and solid carbon byproducts.
View Article and Find Full Text PDFBiodegradation
November 2024
Microbial Resources Division, Research Center for Chemistry, Biology and Agriculture (CPQBA), University of Campinas - UNICAMP, Av. Alexandre Cazellato, 999, Paulínia, SP, 13148-218, Brazil.
Spills of petroleum or its derivatives in the environment lead to an enrichment of microorganisms able to degrade such compounds. The interactions taking place in such microbial communities are complex and poorly understood, since they depend on multiple factors, including diversity and metabolic potential of the microorganisms and a broad range of fluctuating environmental conditions. In our previous study, a complete characterization, based on high-throughput sequencing, was performed in a jet-fuel plume using soil samples and in in-situ microcosms amended with hydrocarbons and exposed for 120 days.
View Article and Find Full Text PDFJ Phys Chem A
November 2024
Molecular Physics, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, Berlin 14195, Germany.
Liquid-jet photoelectron spectroscopy (LJ-PES) and electronic-structure theory were employed to investigate the chemical and structural properties of the amino acid l-proline in aqueous solution for its three ionized states (protonated, zwitterionic, and deprotonated). This is the first PES study of this amino acid in its biologically relevant environment. Proline's structure in the aqueous phase under neutral conditions is zwitterionic, distinctly different from the nonionic neutral form in the gas phase.
View Article and Find Full Text PDFJ Phys Chem Lett
November 2024
School of Chemical Sciences, National Institute of Science Education and Research (NISER), PO Bhimpur-Padanpur, Via Jatni, Khurda District, Bhubaneswar 752050, India.
Aromaticity is a century-old concept that is even introduced in high school textbooks. However, the determination of the order of aromaticity of molecules as simple as furan, thiophene, and selenophene is still challenging. This work describes how different theoretical and experimental methods posit different aromaticity orders.
View Article and Find Full Text PDFWater Res
January 2025
Department of Civil and Environmental Engineering, Princeton University, Princeton, NJ 08544, USA; The Andlinger Center for Energy and the Environment, Princeton University, Princeton, NJ 08544, USA. Electronic address:
The global shift toward net-zero emissions necessitates resource recovery from wet waste. In this study, we demonstrate the first feasibility of combining pilot-scale microbial electrolytic cells (MECs) with hydrothermal liquefaction (HTL) for simultaneous post-hydrothermal liquefaction wastewater (PHW) treatment and efficient hydrogen (H₂) production to meet biocrude upgrading requirements. Long-term single reactor operation revealed that fixed anode potential enabled rapid startup, and low catholyte pH and high salinity were effective in suppression of cathodic methanogenesis and acetogenesis - resulting in high current density of 16.
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