Correction for 'Organic semiconductor perylenetetracarboxylic diimide (PTCDI) electrodes for electrocatalytic reduction of oxygen to hydrogen peroxide' by Magdalena Warczak et al., Chem. Commun., 2018, DOI: .
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Exciton Delocalization and Polarizability in Perylenetetracarboxylic Diimide Probed Using Electroabsorption and Fluorescence Spectroscopies.
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Department of Sciences and Informatics, Muroran Institute of Technology, Mizumoto-cho 27-1, Muroran 050-8585, Hokkaido, Japan.
Perylenetetracarboxylic diimide (PTCDI) is an n-type organic semiconductor molecule that has been widely utilized in numerous applications such as photocatalysis and field-effect transistors. Polarizability and dipole moment, which are inherent properties of molecules, are important parameters that determine their responses to external electric and optical fields, physical properties, and reactivity. These parameters are fundamentally important for the design of innovative materials.
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Institute of Physical Chemistry, University of Innsbruck, 6020 Innsbruck, Austria.
The organic semiconductor 3,4,9,10-perylenetetracarboxylic diimide (PTCDI), a widely used industrial pigment, has been identified as a diffusion-less Na-ion storage material, allowing for exceptionally fast charging/discharging rates. The elimination of diffusion effects in electrochemical measurements enables the assessment of interaction energies from simple cyclic voltammetry experiments through the theoretical work of Laviron and Tokuda. In this work, the two N-substituted perylenes, ,'-dimethyl-3,4,9,10-perylenetetracarboxylic diimide (MePTCDI) and ,'-diphenyl-3,4,9,10-perylenetetracarboxylic diimide (PhPTCDI), as well as the parent molecule 3,4,9,10-perylenetetracarboxylic diimide (HPTCDI) are investigated as thin-film composite electrodes on carbon fibers for sodium-ion batteries.
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Key Laboratory of Subsurface Hydrology and Ecological Effects in Arid Region, Ministry of Education, School of Water and Environment, Chang'an University, Xi'an, 710064, P. R. China.
3,4,9,10-Perylenetetracarboxylic dianhydride (PDI) is one of the best n-type organic semiconductors and an ideal light-driven catalyst for lignin depolymerization. However, the charge localization effect and the excessively strong intermolecular aggregation trend in PDI result in rapid electron-hole (e -h ) recombination, which limits photocatalytic performance. Herein, polymeric carbon nitride/polyhedral oligomeric silsesquioxane PDI (p-CN/P-PDI) S-scheme heterojunction photocatalyst was prepared by the solvent evaporation-deposition method for C-C bond selective cleavage of lignin β-O-4 model.
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Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), Research Center for Carbon Nanomaterials, School of Materials Science and Engineering, Shandong University, Jinan 250061, P. R. China.
Organic electrode materials have shown potential for rechargeable batteries because they are environmentally friendly, earth-abundant sources, recyclable, high sustainable, designable, flexible, and lightweight. However, low electrical conductivity and dissolution in organic liquid electrolytes hinder their further development. Herein, MXene/organics heterostructures are designed to address the problems of organic electrodes via a scalable and simple electrostatic self-assembly strategy.
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Key Laboratory of Luminescence Analysis and Molecular Sensing (Southwest University), Ministry of Education, School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China.
A high initial signal for the sensitive detection of analytes is critical in photoelectrochemical (PEC) biosensing systems. As a semiconductor, 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) possesses an appropriate optical band gap of 2.5 eV and inherently intense and stable PEC response.
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