An AgSCF mediated nucleophilic trifluoromethylthiolation reaction for C(sp)-SCF bond formation is reported. This nucleophilic trifluoromethylthiolation reaction of bromoalkynones afforded various useful ynonyl trifluoromethyl sulfides in high yields. Interestingly, the over-addition of AgSCF is avoided in our approach.
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http://dx.doi.org/10.1039/c8ob00007g | DOI Listing |
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