Optical, Magnetic and Photocatalytic Activity Studies of Li, Mg and Sr Doped and Undoped Zinc Oxide Nanoparticles.

J Nanosci Nanotechnol

The United Nations Educational, Scientific and Cultural Organization (UNESCO)-University of South Africa (UNISA), Africa Chair in Nanoscience's/Nanotechnology Laboratories, College of Graduate Studies, University of South Africa (UNISA), Muckleneuk Ridge, Pretoria, 0003, South Africa.

Published: August 2018

AI Article Synopsis

  • Nanoparticles of Li, Mg, and Sr doped and undoped zinc oxide were synthesized using a simple precipitation method, and their structural, optical, and magnetic properties were analyzed through various techniques such as XRD, SEM, and FTIR.
  • The XRD results confirmed the hexagonal wurtzite structure of all samples, while SEM images showed particle sizes between 10 nm and 50 nm, indicating successful doping.
  • Additionally, the optical analysis revealed changes in bandgap and luminescence due to doping, with pure ZnO being paramagnetic and doped ZnO exhibiting ferromagnetic properties, alongside assessing the photocatalytic activity of the samples.

Article Abstract

Nanoparticles of Li, Mg and Sr doped and undoped zinc oxide was prepared by simple precipitation method. The structural, optical, and magnetic properties of the samples were investigated by the Powder X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM), Fourier Transform Infrared (FTIR) spectroscopy, Ultra-violet Visible spectroscopy (UV-vis) spectra, Photoluminescence (PL) and Vibrational Sample Magnetometer (VSM). The Powder X-ray diffraction data confirm the formation of hexagonal wurtzite structure of all doped and undoped ZnO. The SEM photograph reveals that the pores availability and particles size in the range of 10 nm-50 nm. FTIR and UV-Visible spectra results confirm the incorporation of the dopant into the ZnO lattice nanostructure. The UV-Visible spectra indicate that the shift of blue region (lower wavelength) due to bandgap widening. Photoluminescence intensity varies with doping due to the increase of oxygen vacancies in prepared ZnO. The pure ZnO exist paramagnetic while doped (Li, Mg and Sr) ZnO exist ferromagnetic property. The photocatalytic activity of the prepared sample also carried out in detail.

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http://dx.doi.org/10.1166/jnn.2018.15442DOI Listing

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