Nanoparticles of Li, Mg and Sr doped and undoped zinc oxide was prepared by simple precipitation method. The structural, optical, and magnetic properties of the samples were investigated by the Powder X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM), Fourier Transform Infrared (FTIR) spectroscopy, Ultra-violet Visible spectroscopy (UV-vis) spectra, Photoluminescence (PL) and Vibrational Sample Magnetometer (VSM). The Powder X-ray diffraction data confirm the formation of hexagonal wurtzite structure of all doped and undoped ZnO. The SEM photograph reveals that the pores availability and particles size in the range of 10 nm-50 nm. FTIR and UV-Visible spectra results confirm the incorporation of the dopant into the ZnO lattice nanostructure. The UV-Visible spectra indicate that the shift of blue region (lower wavelength) due to bandgap widening. Photoluminescence intensity varies with doping due to the increase of oxygen vacancies in prepared ZnO. The pure ZnO exist paramagnetic while doped (Li, Mg and Sr) ZnO exist ferromagnetic property. The photocatalytic activity of the prepared sample also carried out in detail.
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http://dx.doi.org/10.1166/jnn.2018.15442 | DOI Listing |
Materials (Basel)
December 2024
School of Materials Science and Engineering, Pusan National University, Busan 46241, Republic of Korea.
We investigated the phase transitions, mechanical properties, and chemical durability of a composition of 9 mol% CaO-stabilized zirconia (9CSZ) doped with 2-4 mol% CeO under thermal stress against molten slag. The monoclinic phase fraction of 9CSZ was 7.14% at room temperature, and CSZ doped with 2-4 mol% CeO showed a slightly lower value of 5.
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January 2025
College of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063210, China.
As a graphene-like material, h-BN has stimulated great research interest recently due to its potential application for next-generation electronic devices. Herein, a systematic theoretical investigation of electronic structures and optical properties of C-doped and Cu-Al co-doped h-BN is carried out by the first-principles calculations. Firstly, two different C-doped h-BN structures for the para-position and ortho-position are constructed.
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December 2024
Department of Chemical Systems Engineering, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan.
Perovskite solar cell (PSC) technology holds great promise with continuously improving power conversion efficiency; however, the use of metal electrodes hinders its commercialization and the development of tandem designs. Although single-walled carbon nanotubes (SWCNTs), as one-dimensional materials, have the potential to replace metal electrodes in PSCs, their poor conductivity still limits their application. In this study, the near-infrared (NIR)-absorbing anionic heptamethine cyanine dye-doped SWCNTs functioned in a dual role as an efficient charge-selective layer and electrode in PSCs.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Soochow University, FUNSOM, CHINA.
Developing durable IrO2-based electrocatalysts with high oxygen evolution reaction (OER) activity under acidic condition is crucial for proton exchange membrane electrolyzers. While oxygen defects are considered potentially important in OER, their direct relationship with catalytic activity has yet to be established. In this study, we introduced abundant oxygen vacancies through Re doping in 2D IrO2 (Re0.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
January 2025
State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, China.
The abrupt drop of resistance to zero at a critical temperature is a key signature of the current paradigm of the metal-superconductor transition. However, the emergence of an intermediate bosonic insulating state characterized by a resistance peak preceding the onset of the superconducting transition has challenged this traditional understanding. Notably, this phenomenon has been predominantly observed in disordered or chemically doped low-dimensional systems, raising intriguing questions about the generality of the effect and its underlying fundamental physics.
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