Light-enhanced acid catalysis over a metal-organic framework.

Chem Commun (Camb)

Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Center of Suzhou Nano Science and Technology, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.

Published: March 2018

A Brønsted acid-functionalized metal-organic framework (MOF), MIL-101-SOH, was prepared for acid-engaged esterification reactions. Strikingly, for the first time, the MOF exhibits significantly light-enhanced activity and possesses excellent activity and recyclability, with even higher activity than HSO under light irradiation.

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http://dx.doi.org/10.1039/c8cc00130hDOI Listing

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