Exploration research on synthesis and application of a new dye containing di-2-picolyamine.

Spectrochim Acta A Mol Biomol Spectrosc

College of Chemistry and Chemical Engineering, Anhui University and Key Labotatory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, 230601 Hefei, PR China. Electronic address:

Published: May 2018

A newly designed fluorescence dye L based on di-2-picolyamine (DPA) moiety as a chelator was obtained under the protection of N at 120°C, and KI as catalyst with relatively better yield. More interestingly, L not only could selectively and sensitively detect Cu ions in aqueous medium but also examine the Cu ions of the actual water samples. Nevertheless, L could be visual in Hela cells with excellent cell permeability, viz, monitoring exogenous Cu ions as well as realizing an "on-off-on" process.

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Source
http://dx.doi.org/10.1016/j.saa.2018.02.023DOI Listing

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