Multicopper oxidases (MCOs) catalyzed two half reactions (linked by an intramolecular electron transfer) through a Ping-Pong mechanism: the substrate oxidation followed by the O reduction. MCOs have been characterized in details in solution or immobilized on electrode surfaces. The nature of the rate-limiting steps, which is controversial in the literature, is discussed in this mini review for both cases. Deciphering such rate-limiting steps is of particular importance to efficiently use MCOs in any applications requiring the reduction of O to water.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5801829 | PMC |
| http://dx.doi.org/10.1016/j.biopen.2017.01.001 | DOI Listing |
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