Adsorption of Cu2+ ions from aqueous solutions is an increasingly important problem. Nano-titanate ETS-2 (Engelhard Titanosilicate-2) was studied for Cu2+ removal from aqueous solutions through the batch technique at room temperature. Structural and chemical properties of both ETS-2 sorbent and aqueous solution were studied by different characterization tests such as Thermogravimetric Analysis, Energy Dispersive X-ray spectroscopy, X-ray Photoelectron Spectroscopy and Inductively Coupled Plasma measuremen. Copper adsorption capacity was found to increase upon raising the contact time or the pH of the solution. The maximum uptake of Cu2+ (99.9%) by ETS-2 occurred at pH of 6.7 and 30 min of contact time. The Cu2+ removal capacity of ETS-2 was found to be 53.58 mg/g at pH = 5.16, which improved to 54.02 mg/g, when rising the contact time to 90 min. Chemical properties of ETS-2 indicated that ETS-2 surface possessed sodium exchange sites making it a favourable sorbent for metal exchange.
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http://dx.doi.org/10.1166/jnn.2018.14698 | DOI Listing |
ACS Omega
January 2025
Department of Chemistry and Biochemistry, University of Colorado Colorado Springs, 1420 Austin Bluffs Parkway, Colorado Springs, Colorado 80918 United States.
The development of a sensitive and selective silver nanoparticle assay for the quantitation of vitamin C (SNaP-C), as ascorbic acid (AA) and total ascorbic acid (TAA = AA + dehydroascorbic acid, DHAA), is described. Three assay parameters were investigated and optimized: (1) synthesis of silver nanoparticles (AgNPs) to produce a reliable enhanced localized surface plasmon resonance (LSPR) in the presence of specific added antioxidants; (2) ensuring long-term stability of AA and DHAA in aqueous solutions; and (3) SNaP-C assay conditions to allow for rapid analysis of samples (beverages) by monitoring the enhanced LSPR. The synthesis of AgNPs using soluble starch as a capping agent and d-arabinose as a reducing agent was optimized in a CEM Discover SP laboratory microwave.
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January 2025
Department of Pharmaceutical Chemistry, College of Pharmacy, King Saud University, P.O. Box 2457, Riyadh 11451, Saudi Arabia.
Carbon dots (CDs) are emerging novel fluorescent sensing nanomaterials owing to their tunable optical properties, biocompatibility, and eco-friendliness. Herein, we report a facile one-pot hydrothermal route for the synthesis of highly green fluorescent CDs using gallic acid (GA) as a single carbon source in ,-dimethylformamide (DMF) solvent, which serves as a nitrogen source and reaction medium. The optical properties of the synthesized GA-DMF CDs were systematically characterized by using UV-vis and photoluminescence spectroscopy, revealing strong green fluorescence.
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January 2025
Department of Chemistry, University at Albany - State University of New York (SUNY), 1400 Washington Avenue, Albany, New York 12222, United States.
The contamination of water with dyes stemming from the discharge of industrial waste poses significant environmental risks and health concerns. In this study, the phytoremediation potential of the wetland plant was investigated (as a function of plant biomass, pH, contact time, and initial dye concentration) for the removal of methylene blue and methyl red dyes from wastewater. The experimental adsorption capacities under the optimum conditions were found to be 1.
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January 2025
Helmholtz Institute Ulm (HIU), Helmholtzstrasse 11, 89081, Ulm, Germany.
Separators are critical components of zinc-metal batteries (ZMBs). Despite their high ionic conductivity and excellent electrolyte retention, the widely used glass fiber (GF) membranes suffer from poor mechanical stability and cannot suppress dendrite growth, leading to rapid battery failure. Contrarily, polymer-based separators offer superior mechanical strength and facilitate more homogeneous zinc (Zn) deposition.
View Article and Find Full Text PDFAnal Chem
January 2025
MOE Key Laboratory of Geriatric Nutrition and Health, Department of Bioengineering, Beijing Technology and Business University, Beijing 100048, China.
Multiplexed microRNA (miRNA) detection has proven valuable in disease diagnosis; yet, the development of advanced tools for their analysis remains a subject of broad interest. Here, we propose a novel single-particle method for multiplexed miRNA detection using self-directed hydrogel microspheres, which feature supersegmented compartments for loading analyte probes and an air-encapsulated region that grants the microsphere a unique preferred posture in aqueous solutions. By exploiting microfluidic technology, we can widely adjust the size of the microspheres and the number of compartments can be widely adjusted.
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