Crystal structure of the η-ketimine titanium complex (di-phenyl-amido-κ){3-methyl-6-[(4-methyl-phen-yl)(phenyl-aza-nid-yl)methyl-idene]cyclo-hexa-2,4-dien-1-yl-κ,}(η-penta-methyl-cyclo-penta-dien-yl)titanium(IV).

The mol-ecular structure of the title titanium(IV) half-sandwich complex, [Ti(η-CH)(η-CHN)(CHN)], shows a three-legged piano-stool geometry at the central Ti atom, comprising of one penta-methyl-cyclo-penta-dienyl ligand, one bidentate ketimine ligand in an η-coordination mode and one monodentate di-phenyl-amide ligand. Except for van der Waals forces, there are no significant inter-molecular inter-actions in the crystal.