Motivated by the evaporation of soap films, which has a significant effect on their lifetime, we performed an experimental study on the evaporation of vertical surfaces with model systems based on hydrogels. From the analogy between heat and mass transfer, we adopt a model describing the natural convection in the gas phase due to a density contrast between dry and saturated air. Our measurements show a good agreement with this model, both in terms of scaling law with the Grashof number and in terms of order of magnitude. We discuss the corrections to take into account, notably the contribution of edge effects, which have a small but visible contribution when lateral and bottom surface areas are not negligible compared to the main evaporating surface area.
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http://dx.doi.org/10.1039/c7sm01902e | DOI Listing |
ACS Nano
January 2025
Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, United States.
With their ability to self-assemble spontaneously into well-defined nanoscale morphologies, block copolymer (BCP) thin films are a versatile platform to fabricate functional nanomaterials. An important challenge to wider deployment of BCPs in nanofabrication is combining precise control over the nanoscale domain orientation in BCP assemblies with scalable deposition techniques that are applicable to large-area, curved, and flexible substrates. Here, we show that spray-deposited smooth films of a nominally disordered BCP exhibit latent orientations, which can be prescriptively selected by controlling solvent evaporation during spray casting.
View Article and Find Full Text PDFLangmuir
January 2025
Materials Science and Engineering, Drexel University, 3141 Chestnut Street, Philadelphia, Pennsylvania 19104, United States.
The functional performance of a particulate thin film depends greatly on the particle distribution that forms during drying. In situ methods for monitoring the impact of different processing parameters on the distribution of particles currently require expensive and specialized equipment. This work addresses this gap by miniaturizing a geophysical prospecting method to thin-film applications.
View Article and Find Full Text PDFBiomaterials
May 2025
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, 2999 North Renmin Road, Shanghai, 201620, China.
Moisture induced by wound exudate is crucial throughout the wound repair process. The dressing directly affects the absorption, permeation, and evaporation of the wound exudate. However, most dressings in clinical often result in excessive dryness or moisture of wound due to their monotonous structure and function, leading to ineffective thermodynamic control of evaporation enthalpy.
View Article and Find Full Text PDFInt J Phytoremediation
December 2024
Department of Process Engineering, Faculty of Technology, University of El Oued, El Oued, Algeria.
Phytoremediation is an effective and sustainable method for removing pollutants from wastewater. This study investigates the phytoremediation capabilities of , a halophytic Saharan plant species, for excess phosphorus and nitrogen in domestic wastewater. The plants were sourced from the "" wetland, a wastewater discharge area in the north of El-Oued, south-eastern Algeria.
View Article and Find Full Text PDFAdv Mater
December 2024
Hefei National Research Center for Physical Sciences at the Microscale, School of Chemistry and Materials Science, Key Laboratory of Energy Conversion Materials, Chinese Academy of Sciences, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
Crystallization process is critical for enhancing the crystallinity, regulating the crystal orientation of polycrystalline thin films, as well as repairing defects within the films. For quasi-1D SbSe photovoltaic materials, the preparation of SbSe thin films still faces great challenges in adjusting orientation and defect properties, which limits the device performance. In this study, a novel post-treatment strategy is developed that uses a low melting point BO coating layer as a flux to drive the recrystallization of SbSe, thereby regulating the micro-orientation of thermal evaporation-derived SbSe films and optimizing their electrical properties.
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