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Dearylation of arylphosphine oxides using a sodium hydride-iodide composite. | LitMetric
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Dearylation of arylphosphine oxides using a sodium hydride-iodide composite.

Ciputra Tejo Jia Hao Pang Derek Yiren Ong Miku Oi Masanobu Uchiyama Ryo Takita Shunsuke Chiba

Chem Commun (Camb)

Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.

Published: February 2018

A new protocol for the dearylation of arylphosphine oxides was developed using sodium hydride (NaH) in the presence of lithium iodide (LiI). The transient sodium phosphinite could be functionalized with a range of electrophiles in a one-pot fashion.

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 Source
http://dx.doi.org/10.1039/c8cc00289dDOI Listing

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