https://eutils.ncbi.nlm.nih.gov/entrez/eutils/efetch.fcgi?db=pubmed&id=29377686&retmode=xml&tool=Litmetric&email=readroberts32@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09 293776862018060820180608
1520-512614062018Feb14Journal of the American Chemical SocietyJ Am Chem SocInterlocked Supramolecular Polymers Created by Combination of Halogen- and Hydrogen-Bonding Interactions through Anion-Template Self-Assembly.204120452041-204510.1021/jacs.7b12612We present the synthesis and oxoanion-assembling properties of a monomer with a naphthalene ring as a central core decorated with two arms containing iodotriazolium rings as anion binding sites. Interactions with SO42-, H2PO4-, and HP2O73- anions, via a cooperative mechanism, afforded new supramolecular materials stabilized by a combination of halogen- and hydrogen-bonding interactions. 1H NMR experiments and solid-state structure provided evidence for the initial formation of a supramolecular linear chain, nucleation step, and then two different supramolecular chains are interpenetrated with each other, elongation steps, involving the formation of hydrogen bonds between two oxygens of the anion from one of the chains and the naphthalene inner protons from the other chain. Scanning electron microscopy studies revealed that the morphology of the crystals changed dramatically with the nature of the anion added.ZapataFabiolaFDepartamento de Química Orgánica, Universidad de Murcia , Campus de Espinardo, 30100 Murcia, Spain.GonzálezLidiaLDepartamento de Química Orgánica, Universidad de Murcia , Campus de Espinardo, 30100 Murcia, Spain.CaballeroAntonioA0000-0002-8229-6866Departamento de Química Orgánica, Universidad de Murcia , Campus de Espinardo, 30100 Murcia, Spain.BastidaAdolfoADepartamento de Química Física, Universidad de Murcia , Campus de Espinardo, 30100 Murcia, Spain.BautistaDeliaDServicio de Apoyo a la Investigación, Universidad de Murcia , Campus de Espinardo, E-30071 Murcia, Spain.MolinaPedroP0000-0001-8568-9449Departamento de Química Orgánica, Universidad de Murcia , Campus de Espinardo, 30100 Murcia, Spain.engJournal ArticleResearch Support, Non-U.S. Gov't20180202
United StatesJ Am Chem Soc75030560002-7863
201813060201813061201813060ppublish2937768610.1021/jacs.7b12612