A stable thiolato-Cu-thiolato triple linkage that bridges two cobalt(iii) centres.

Dalton Trans

Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.

Published: February 2018

Treatment of Λ-fac-[Co(d-pen-N,S)] (d-Hpen = d-penicillamine) with Cu in water gave a stable CoCu complex, ΛΛ-[CoCu(d-pen)] ([1]), having three thiolato-copper(i)-thiolato moieties that bridge two cobalt(iii) centres. Complex [1] was isolated as a coordination polymer of Na[1], which was converted to a complex salt of [Cr(HO)][1] by treatment with Cr(NO).

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http://dx.doi.org/10.1039/c7dt04760fDOI Listing

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