An Orbital Trap Mass Analyzer Using a Hybrid Magnetic-Electric Field: A Simulation Study.

J Am Soc Mass Spectrom

Department of Chemistry and Laser Chemistry Institute, Fudan University, 220 Handan Road, Shanghai, 200433, China.

Published: March 2018

An orbital ion trap mass analyzer employing hybrid magnetic-electric field was designed and simulated. The trap has a rotational symmetrical structure and the hybrid trapping field was created in a toroidal space between 12 pairs of sector detection electrodes. Ion injection and ion orbital motion inside the trap were simulated using SIMION 8.1 with a user Lua program, and the required electric and magnetic field were investigated. The image charge signal can be picked up by the 12 pairs of detection electrodes and the mass resolution was evaluated using FFT. The simulated resolving power for the optimized configuration over 79,000 FWHM was obtained at the magnetic induction intensity of 0.5 Tesla in the simulation. Graphical Abstract ᅟ.

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http://dx.doi.org/10.1007/s13361-017-1868-8DOI Listing

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