Plasmonic behaviour and plasmon-induced charge separation of nanostructured MoO under near infrared irradiation.

Nanoscale

Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan.

Published: February 2018

Plasmon-induced charge separation (PICS) allows direct conversion of localized surface plasmon resonance (LSPR) to electron flows and photoelectrochemical reactions. However, PICS has only been achieved using plasmonic noble metal nanoparticles, not with compound nanoparticles. In order to achieve compound PICS, MoO nanostructures were prepared that exhibit LSPR in the near infrared region by using metal oxides or metal nanoparticles as templates. Solid-state cells based on the MoO nanostructure were developed. Their photoresponse to 700-1400 nm infrared light was investigated and analyzed on the basis of their PICS mechanisms.

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http://dx.doi.org/10.1039/c7nr09477aDOI Listing

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