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Photochemical transformation of acifluorfen under laboratory and natural conditions.

Pest Manag Sci

April 2001

Laboratoire de Photochimie Moléculaire et Macromoléculaire, UMR CNRS No. 6505, F-63177 Aubière, France.

Acifluorfen was irradiated in pure water at various excitation wavelengths and pH values. Numerous photoproducts were obtained which were identified by [1H]NMR and/or HPLC-MS/MS. The main reaction pathways were photo-decarboxylation, photo-cleavage of the ether bonding with formation of phenolic compounds, photo-dechlorination and photo-Claisen type rearrangement.

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