Well-defined diazotates are scarce. Here we report the synthesis of unprecedented homoleptic palladium(II) diazotate complexes. The palladium(II)-mediated nitrosylation of 2-aminopyridines with NaNO results in the formation of metal-stabilized diazotates, which were found to be cytotoxic to human ovarian cancer cells.

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http://dx.doi.org/10.1021/acs.inorgchem.8b00072DOI Listing

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