Methane seepage from the upper continental slopes of Western Svalbard has previously been attributed to gas hydrate dissociation induced by anthropogenic warming of ambient bottom waters. Here we show that sediment cores drilled off Prins Karls Foreland contain freshwater from dissociating hydrates. However, our modeling indicates that the observed pore water freshening began around 8 ka BP when the rate of isostatic uplift outpaced eustatic sea-level rise. The resultant local shallowing and lowering of hydrostatic pressure forced gas hydrate dissociation and dissolved chloride depletions consistent with our geochemical analysis. Hence, we propose that hydrate dissociation was triggered by postglacial isostatic rebound rather than anthropogenic warming. Furthermore, we show that methane fluxes from dissociating hydrates were considerably smaller than present methane seepage rates implying that gas hydrates were not a major source of methane to the oceans, but rather acted as a dynamic seal, regulating methane release from deep geological reservoirs.
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http://dx.doi.org/10.1038/s41467-017-02550-9 | DOI Listing |
Inorg Chem
January 2025
Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, United States.
Using ab initio based molecular dynamics and electronic structure calculations, we show that Zn impurities in hydrated amorphous calcium carbonate (ACC) have a much lower coordination number than other divalent impurities due to covalent interactions between the 3d Zn shell and the oxygen atoms of the carbonate and water groups. The local structure around Zn in ACC, including the predicted low coordination number, is confirmed by X-ray absorption spectroscopy of synthetic Zn-bearing ACC. The strong Zn-O chemical interaction leads to substantial water dissociation and slightly disrupts the hydrogen bonding network.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Department of Chemistry, School of Science, Tianjin University, Tianjin, 300072, China.
Electrochemical reductive deuteration of nitriles is a promising strategy for synthesizing deuterated amines with DO as the deuterated source. However, this reaction suffers from high overpotentials owing to the sluggish DO dissociation kinetics and high thermodynamic stability of the C≡N triple bond. Here, low-coordinated copper (LC-Cu) is designed to decrease the overpotential for the electrosynthesis of the precursor of Melatonin-d, 5-methoxytryptamine-d, by 100 mV with a 68 % yield (Faradaic efficiency), which is 4 times greater than that of high-coordinated copper (HC-Cu).
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Gansu Industry Technology Center of Transportation Construction Materials Research and Application, Lanzhou Jiaotong University, Lanzhou 730070, China.
In order to study the effect of the crushing process on the fine separation of reclaimed asphalt pavement (RAP) and the mechanical properties of cement-stabilised aggregate mixed with RAP, four crushing processes, namely small mesh hammer crushing, hammer crushing, jaw crushing, and double roller crushing, were used to separate the aggregate from asphalt in RAP materials. The effect of crushing on the grading characteristics and agglomeration condition of RAP material was investigated. RAP cement-stabilised aggregates were prepared and analysed for their mechanical properties and micro-morphology using RAP materials obtained from fine separation.
View Article and Find Full Text PDFNat Commun
January 2025
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China.
The development of mechanically robust super-lubrication hydrogel materials with sustained lubricity at high contact pressures is challenging. In this work, inspired by the durable lubricity feature of the earthworm epidermis, a multilevel structural super-lubrication hydrogel (MS-SLH) system, the so-called lubricant self-pumping hydrogel, is developed. The MS-SLH system is manufactured by chemically dissociating a double network hydrogel to generate robust and wrinkled lubrication layer, and then laser etching was used to generate cylindrical texture pores as gland-like pockets for storing lubricants.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Department of Petroleum Engineering, School of Energy Technology, Pandit Deendayal Energy University, Gandhinagar, Gujarat 382426, India. Electronic address:
Naturally occurring gas clathrates are a significant methane resource-the primary component of natural gas, regarded as the cleanest hydrocarbon and a key feedstock for producing gray and blue hydrogen. Despite the global abundance of gas hydrate reserves, extraction via depressurization has yet to achieve commercially viable production rates. The primary limitation lies in the low permeability of hydrate-bearing sediments, where solid clathrates obstruct porous pathways, hindering dissociation and slowing gas recovery.
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