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Evidence for Aggregation-Induced Emission from Free Rotation Restriction of Double Bond at Excited State. | LitMetric
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Evidence for Aggregation-Induced Emission from Free Rotation Restriction of Double Bond at Excited State.

Jia-Bin Xiong Ying-Xue Yuan Lian Wang Jian-Ping Sun Wei-Guo Qiao Hong-Chao Zhang Miao Duan Hongwei Han Song Zhang Yan-Song Zheng

Org Lett

Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.

Published: January 2018

This paper reports that cis-TPE dicycles emit strong fluorescence, while the gem dicycles show almost no emission in solution, demonstrating that the free rotation restriction of the double bond at the excited state is the key factor for AIE effects.

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 Source
http://dx.doi.org/10.1021/acs.orglett.7b03662DOI Listing

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