On the basis of their potential passivating characteristics, in this study, borates have been used to synthesize a novel slow-release inhibitor to suppress long-term mild steel corrosion in simulated recirculating water. The passivating performance was characterized by various electrochemical measurements and the passivating mechanism was interpreted by the point defect model. The experimental results indicated that the slow-release inhibitor exhibited a passivating efficiency of over 98% after 30 days of immersion, due to the formation of a passive film that was predominant by a Fe-O-B structure on the mild steel surface. This study provides a novel controlled-release concept and a slow-release borate inhibitor to control long-term corrosion.
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http://dx.doi.org/10.1021/acsami.7b15507 | DOI Listing |
RSC Adv
January 2025
Materials and Natural Product Laboratory, Department of Chemistry, Chandigarh University Gharuan-140413 Mohali Punjab India
Mild steel provides strength to various building and industrial materials but it is badly affected by corrosion. In the present study, we investigate the efficacy of , a plant-based green corrosion inhibitor to minimize mild steel corrosion in a 1 M HSO solution. Weight loss, surface coverage, inhibition efficiency, and corrosion rate measurements were evaluated for various inhibitor concentrations and time intervals.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
School of Chemistry and Chemical Engineering, Jiangsu University, 301 Xuefu Rd., Zhenjiang, Jiangsu 212013, China. Electronic address:
The development of an efficient coating with comprehensive antimicrobial and anticorrosion properties for metals is crucial. The present study used a one-pot strategy to fabricate a high-performance nanocomposite coating of carboxylated nitrile butadiene rubber/cellulose nanofibers/zinc oxide (XNBR/CNF-ZnO), demonstrating excellent potential for application in the protection against metal corrosion. Eco-friendly CNF-ZnO nanomaterials, prepared using the in-situ generation method, were used as reinforcing fillers, while XNBR was used as the matrix material.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Chemistry, Sahyadri Science College, Shivamogga, Karnataka, 574146, India.
Newly synthesized 1-bromo-2-(4-bromophenylsulfonate)-4,4-dimethyl-1-cyclohexenyl-6-one (CHD) as a potential anticorrosive agent in an acidic medium at an elevated temperature range of 305-335 K. This synthesized compound confirmed by spectral characterizations and it acts as a coating on mild steel surfaces in 1 M Hydrochloric acid (HCl) solution through electrochemical reactions. The synthesis of the compound has been discussed, and the Infrared (IR) and Nucleic Magnetic Resonance (NMR) spectral analysis confirmed the derivative.
View Article and Find Full Text PDFACS Omega
December 2024
Department of Inorganic Chemistry, Universidade Federal do Rio de Janeiro UFRJ, Avenida Athos da Silveira Ramos, 149, Cidade Universitária, 21941-909 Rio de Janeiro, Brazil.
This work reports the obtention of Si,N,S-CQDs from sugar cane bagasse and their inhibitory action on the mild steel corrosion in 1 mol L HCl solution. The CQDs were successfully obtained and characterized by X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, Dynamic light scattering, Raman, and UV-vis techniques, also showing endogenous self-doping. The anti-corrosive activity of CQDs was investigated by gravimetric tests, potentiodynamic polarization curves, electrochemical impedance measurements, atomic force microscopy, and scanning electron microscopy.
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