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Towards Efficient and Photostable Red-Emitting Photonic Materials Based on Symmetric All-BODIPY-Triads, -Pentads, and -Hexads.
Chemistry
November 2019
Instituto de Química Organica General (IQOG-CSIC), Juan de la Cierva 3, 28006, Madrid, Spain.
The development of efficient and stable red and near-IR emitting materials under hard radiation doses and/or prolonged times is a sought-after task due to their widespread applications in optoelectronics and biophotonics. To this aim, novel symmetric all-BODIPY-triads, -pentads, and -hexads have been designed and synthesized as light-harvesting arrays. These photonic materials are spectrally active in the 655-730 nm region and display high molar absorption across UV-visible region.
View Article and Find Full Text PDFThe glycaemic sixer [glycaemic hexad].
J Pak Med Assoc
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Department of Endocrinology, Bharti Hospital, Karnal, India.
This opinion piece describes a cricket-based analogy, the Glycaemic Sixer, for diabetes care. The hexad lists six glycaemic parameters which must be targeted to achieve optimal cardiovascular outcomes. All six parameters, i.
View Article and Find Full Text PDFPentads and Hexads in Diabetes Care: Numbers as Targets; Numbers as Tools.
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Department of Cardiology, Rama Specialty Hospital, Karnal, India.
Conformational dynamics of the human propeller telomeric DNA quadruplex on a microsecond time scale.
Nucleic Acids Res
February 2013
Centre for Cancer Research and Cell Biology, Queen's University of Belfast, Belfast BT9 7BL, UK.
The human telomeric DNA sequence with four repeats can fold into a parallel-stranded propeller-type topology. NMR structures solved under molecular crowding experiments correlate with the crystal structures found with crystal-packing interactions that are effectively equivalent to molecular crowding. This topology has been used for rationalization of ligand design and occurs experimentally in a number of complexes with a diversity of ligands, at least in the crystalline state.
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J Am Chem Soc
February 2011
International Center for Materials Nanoarchitectonics, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan.
Article Synopsis
- - The Merrifield solid-phase peptide synthesis method has been modified for creating metal−organic complex arrays (MOCAs) with both similar and different metal ions.
- - A special L-tyrosine derivative, which is protected and has a terpyridine component, was reacted with various metal ions (Pt(II), Rh(III), and Ru(II)) to form complex structures in a specific sequence.
- - These metal complexes were successfully detached from the polymer resin, and their identities were verified using mass spectrometry.
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